Investigating Uranium In Drinking Water
July 1, 2009
A
few years back, the Nebraska Department of Health and Human Services (DHHS)
began testing all of the water supply wells across Nebraska to be sure they
were in compliance with the new uranium mass regulation promulgated by the U.S.
Environmental Protection Agency. This new regulation established a maximum
contaminant level (MCL) of 30 ug/L for uranium in drinking water. Tom
Christopherson, program manager for water well standards of DHHS, soon learned
that the old public water supply (PWS) wells in the small farming community of
Clarks in central Nebraska were contaminated with uranium at concentrations
between 100 ug/L to 200 ug/L. This was bad news for the approximately 375
residents of Clarks. After a difficult search, two test wells were installed
about 1.5 miles northeast of town, and both wells were non-detect for uranium.
Two new PWS wells were installed adjacent to the test wells, and initial
pumping and testing found that the new north well was yielding water with
uranium concentrations about 30 ug/L. After initial testing was done by the
University of Nebraska-Lincoln, it became apparent that a modified, low-speed
pumping program was not going to correct the problem. It was then that Tom Christopherson
asked if Geoprobe Systems would demonstrate direct-push methods at the site,
and assist the agency in understanding the cause of the elevated uranium
problem at the Clarks well field.
Led by Wes McCall, a Geoprobe environmental geologist, a team of research and
development (R&D) engineers mobilized equipment to Clarks and performed a
4-day expedited investigation at the new well field. According to McCall,
“Going to sites such as this allows us to test new techniques and tooling in real-world
applications. Not only was this a great site to test our new tooling, but we
were also able to help a small community in need of safe drinking water.”
Below the Surface
Using a hydraulic profiling tool (HPT), five HPT logs were collected across the
well field site. A Geoprobe 6625CPT machine and the HPT system were used to
gather information on the local hydrostratigraphy at depths approaching 120
feet. “HPT logs allowed us to ‘see’ subsurface information,” McCall explains. “It
helped us to plan the placement of monitoring wells during the next steps in
the project.”
The next day, another team arrived for monitoring well installation using
direct-push (DP) methods. “Based on the information displayed in the HPT logs,”
McCall recounts. “0.75-inch ID pre-packed screen wells were installed at
selected depths adjacent to the HPT log location.” Five-foot pre-packs were
installed in the aquifer between the fine-grained lenses that were identified
by the HPT logs.
During this process, the R&D team used the new Model 8040DT machine to
advance 2.25-inch (OD) rods up to 118 feet deep. A new Model GS2250 grout
machine performed bottom-up tremie grouting with a 25-percent-solids bentonite
slurry. A second set of pre-packed screen wells were installed at some distance
from both of the PWS wells.
One-half-inch polyethylene tubing and tubing bottom check valves were used for
the initial development of the 0.75-inch pre-packed screen wells. The 12-volt
Geoprobe electric actuator powered the check valve system to develop the wells
up to 115 feet deep. The check valves were moved across the screen interval to
surge and purge between 5 gallons and 20 gallons from each well. After the
initial development significantly lowered the turbidity, mechanical bladder
pumps were installed to perform low-flow purging and sampling. Electric
actuators also powered the bladder pumps at flow rates between approximately
150 ml./min. to 300 ml./min. Flow from the pumps was directed through a small
flow cell equipped with a YSI556 multi-parameter probe to monitor water-quality
parameters. Turbidity was monitored periodically with a Cole Parmer turbidity
meter. Turbidity was below 10 (NTU) in all of the wells prior to sampling. DHHS
personnel collected samples for several cations, anions and trace elements,
including uranium, from each of the newly installed pre-packed screen wells.
“Since one of the 4-inch test wells had shown elevated uranium from earlier
sampling,” McCall explains, “both of these wells were sampled for all of the
analytes and uranium using mechanical bladder pumps and the electric
actuators.”
Samples from all nine of the DP-installed pre-packed screen wells, and the two
4-inch test wells were collected by DHHS personnel and submitted to the
Nebraska State Laboratory for analysis. According to a brief summary of the
chemistry for the A-group wells, which were installed near the south PWS well,
the specific conductance, sodium (Na), sulfate (SO4), selenium (Se) and uranium
(U) all tended to decrease with depth. McCall explains, “However, the results
for the south 4-inch test well, near the A-Group DP wells, appeared anomalous.
Although the test well was screened deep in the aquifer, it had chemistry
similar to the shallow DP wells (A4 & A3), and was out of equilibrium with
the deep DP wells (A1 & A2) screened at similar depths. Based on HPT log
information and well data, the gravel-packed annulus of the old 4-inch test
well was behaving as a conduit for shallow ground water to move down to depth
in the aquifer, especially when the PWS well pumps were activated.” Probably
most obvious is the uranium in the south 4-inch test well. “Data indicates that
the uranium levels in the south test well are 168 ug/L, which is about five times
higher than anything observed in the nearby A-Group wells for uranium McCall
adds. “This definitely is not in equilibrium with the A1 and A2 DP wells
screened at similar depths, which are both non-detect for
uranium.”
Results for the B-group wells show that specific conductance, Na, SO4 and Se
again tend to decrease with depth. However, uranium concentrations are
distinctly higher in the B4 and B3 wells – up to 376 ug/L. According to McCall,
“It appears that these two zones in the aquifer are probable sources for the
uranium observed in the south 4-inch test well and the PWS wells.” By observing
the construction information of the south PWS well, the filter pack extends up
to approximately 60 feet below grade. This means that the filter pack for this
well directly intersects the B3 zone of the aquifer with the high uranium
concentrations. “It becomes apparent,” he notes, “that both the filter-packed
annulus of the original test wells and the extended filter pack of the PWS
wells allow for movement of ground water from shallow zones of the aquifer
downward into the well screen.”
The Right Equipment
It’s important to note that all of the field investigation activities described
here took place in less than a week on-site. That’s nine prepacks set to depths
up to 110 feet, for a total of 609 feet of prepack
installation.
“This was a good project to demonstrate the ability of the new 8040DT machine,”
notes Tom Christy, Geoprobe vice president. “The installations went faster and
smoother than anything we could have achieved with our other model probe
machines.”
Christy also notes that this project sets a good example for the use of
direct-push logging data. “We sent the HPT unit out there a day ahead of time.
The logs we got were very informative, showing us clay and fine-grained zones
that previous investigations of the site by drilling just were not able to pick
up. We knew exactly where to set our prepacks to get a good, multi-level
picture of the distribution of uranium. As a result, all of the prepacks
developed and yielded good samples for analysis.”
Based on knowledge of the geology, the contamination is not caused by human
activity, but rather the uranium occurs naturally in the sediments of the
aquifer. There also is some uranium in the soil outside your window and in the
soil most everywhere on the planet. And actually, the uranium in the soil
outside your window may be 10 times to 100 times the concentration in the
drinking water the people in the community of Clarks were drinking, McCall
explains.
Ultimately, the uranium in the aquifer sediments below Clarks comes from the
sedimentary rocks in eastern Wyoming and also from the granites in the Rocky
Mountains. The rivers erode the sedimentary rocks and granites, and carry the
sand, silt, clay and gravels down the Platte River – along with the uranium
inside of them. These sediments now make up the aquifer materials in the Platte
River and Village of Clarks water supply aquifer.
According to McCall, the real problem is exposure to the uranium. “We don’t eat
the soil, and we usually don’t put our dirty hands in our mouths,” he says. “We
usually don’t inhale much of it either, even on dry windy days in the central
plains. So we don’t actually get
‘exposed.’”
Unfortunately for the people in Clarks, the small amount of uranium in the
sediments in their aquifer (probably only a few parts per million) is
dissolving a little in the ground water due to the ground water chemistry in
some parts of the aquifer. This dissolved uranium gets pulled in by the pump in
their supply wells and it gets to their water tap at home. “The residents of
Clark drink the water or cook with the water,” McCall says, “and so ingest it
and are ‘exposed.’ It seems the primary concern with uranium is not its
radioactive decay in the body (though that’s not good), but the effects uranium
has on our kidneys as a heavy metal causing damage to the organs.”
The Next Step
Currently, the community of Clarks is having the test wells properly abandoned,
and is evaluating corrective measures for the new PWS wells to come back into
compliance with the 30 ug/L uranium MCL.
McCall concludes, “While we’re more familiar investigating problems with man-made
contaminants – like gasoline or TCE in our aquifers – this project demonstrates
that naturally occurring materials, such as uranium or arsenic, can be a
significant problem.” He also states that this project reveals that the same
direct-push methods the industry has applied for the investigation of other
contaminants work well to understand the presence and distribution of naturally
occurring analytes. “It’s easy to imagine how differently the PWS well design
and construction would have progressed,” McCall concludes, “if the data from
the small DP wells had been available before the project was
started.”
Although finding uranium in their drinking water wasn’t good news for the
people in Clarks, having the ability to test new products on sites such as this
is beneficial, having a positive impact on the industry. New technology and
product improvements to better the environment are a direct result of being
able to test equipment and new ideas. It’s also a good reminder of why the
direct-push method is good for both the environment and for those who work in
this industry. Although the levels of uranium were high in the ground water, at
no time was the site team exposed to contaminants, nor were there hazards to
their safety. There were no waste cuttings generated at the site, which
eliminated the need for handling, storage, sampling, analyzing, transporting or
disposing of the contaminated waste – both a risk to health and a costly
investment. ND
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